Gaussian 03W

Introduction

Gaussian 03W is a complete implementation of Gaussian 03 for the Windows environment.

Gaussian 03W can be used to model many properties

  • Energies using a wide variety of methods, including Hartree-Fock, Density Functional Theory, MP2, Coupled Cluster, and high accuracy methods like G3, CBS-QB3 and W1U.
  • Geometries of equilibrium structures and transition states (optimized in redundant internal coordinates for speed), including QST2 transition structure searching.
  • Vibrational spectra, including IR, non-resonant and pre-resonance Raman intensities, anharmonic vibrational analysis and vibration-rotation coupling.
  • Magnetic properties, including NMR chem-ical shifts and spin-spin coupling constants.
  • Spectra of chiral molecules: optical rotations, VCD and ROA.
  • G tensors and other contributions to hyper-fine spectra.

Gaussian 03W can study compounds and reactions under a wide range of conditions:

  • In the gas phase and in solution.
  • In the solid state, using the Periodic Boundary Conditions facility.
  • Excited states can be studied with several methods: CASSCF and RASSCF, Time Dependent DFT and SAC-CI.
  • The Atom Centered Density Matrix Propagation (ADMP) method can be used to perform molecular dynamics simulations in order to study reaction paths and product state distributions.

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